Flow induced crystallization

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August undefined, 2024

WebWe systematically investigate the detailed structure in the flow-induced crystallization of a lightly cross-linked high-density polyethylene as a model semicrystalline polymer sample … WebNov 2, 2024 · The flow-induced formation and relaxation of the representative oriented shish-kebab structure were studied with synchrotron small-angle X-ray scattering (SAXS) method. The flow duration was varied from 2 to 6 s at an identical strain rate to reveal the effect of flow time on stability and dimension …

(PDF) Flow-induced crystallization of a polyethylene liquid …

WebOct 10, 2024 · In flow induced crystallization (FIC) of polymer, the effective extension of molecular chains can dramatically change the structural dynamics and final morphology. Hierarchical structure formation can be controlled by flow parameters, leading to different macroscopic material properties. With complex chain structures such as polydispersity ... WebJul 1, 2013 · Molecular properties are reflected in the rheological and crystallization behavior. The first task is to design and use some well‐defined experiments that … flipping the middle finger images

Flow-induced crystallization of polylactides - The Society of …

WebJan 8, 2024 · Flow-induced crystallization in polymers is an important problem in both fundamental polymer science and industrial polymer processing. The key process of flow-induced nucleation occurs on a … WebJul 6, 2024 · Flow-induced crystallisation of polymers from aqueous solution Introduction. In the natural world numerous strategies for efficient processing of materials have evolved 1, 2, and one... Results. PEO is crystallisable and water soluble, due to the similarity of its … We would like to show you a description here but the site won’t allow us. WebJan 14, 2024 · The flow history had a great influence on the crystallization of pure PP. Beyond 50 s −1, crystallization occurred at a high temperature, suggesting that flow-induced crystallization took place. flipping the pain care model

Understanding flow-induced crystallization in polymers: A …

Flow-induced crystallization of propylene/ethylene random

WebDec 10, 2016 · The well dispersed OXA fibrils and shear flow induced PLLA chain orientation are responsible for the fast crystallization of the PLLA/OXA-240 samples. In … Web19 rows · Jun 22, 2024 · The flow-induced crystallization (FIC) is commonly encountered in the polymer industry as more ... greatest tag team of all timeWebFeb 18, 2024 · The effects induced by the flow on polymer crystallization behavior can be summarized into three aspects, namely accelerated nucleation rate, modified crystal morphology, and newly formed crystal structure, which are all directly relevant to the end-use properties [11, 19].To attain the ultimate goal of predicting the polymer … greatest tag teams

"WebThe nonlinear dynamics in film blowing process is simulated employing the governing equations of the system that include the flow-induced crystallization (FIC), i.e., the continuity, the two force balances (axial and circumferential), the energy, the crystallinity, and the constitutive equations of Phan-Thien Tanner (PTT) model. " - Flow induced crystallization

Flow induced crystallization

WebFlow-induced nucleation and crystallization are observed in conjugated small molecules and polymers, and are closely related to the flow-induced polymer conformational changes and enhanced mass and heat transfer observed during crystallization. WebThe remaining of the paper is divided in two parts. In the first part of the review, the basics of polymer crystallisation are summarized; the main factors acting on the process are …

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WebThe Role of Macromolecular Architecture in Flow-Induced Crystallization. RESEARCHER: Bo Shen. Semicrystalline polymers are processed predominantly from the melt, for … WebFlow-induced crystallization (FIC) is a typical nonequilibrium phase transition and a core industry subject for the largest group of …

WebMay 22, 2015 · Flow-induced crystallisation (FIC) in polymers 1-3 is a central problem in polymer science. Flow dramatically enhances the nucleation rate, leading to much faster crystallisation kinetics and ...

WebFeb 6, 2024 · Abstract. The recently reported crystallization-induced diastereomer transformation (CIDT) of a precursor to navoximod was investigated using online HPLC via a modified EasySampler probe that enables selective solution phase sampling of heterogeneous reaction mixtures. By employing both chiral and achiral stationary … WebApr 9, 2024 · Nafar Sefiddashti, M.H.; Edwards, B.J.; Khomami, B. Atomistic Simulation of Flow-Induced Microphase Separation and Crystallization of an Entangled Polyethylene Melt Undergoing Uniaxial Elongational Flow and the Role of Kuhn Segment Extension. Polymers 2024, 15, 1831. https: ...

WebApr 9, 2024 · At high flow strength, a flow-induced crystallization (FIC) occurred, producing a semicrystalline material possessing a high degree of crystallinity and primarily a monoclinic lattice structure ...

WebBased on classical nucleation theory, the current entropic reduction model (ERM) of flow-induced crystallization (FIC) treats external work as perturbation on the framework of equilibrium thermodynamics, which, however, obscures the nonequilibrium nature of FIC. In this work, in situ investigation on FIC under strong flow by combining a unique … greatest tag teams of all timeWebJan 1, 2016 · A modeling framework was presented to describe flow-induced crystallization of iPP at elevated pressures in multiple crystal phases and morphologies. The framework was constructed by … flipping the script renee coxWebJul 29, 2024 · Abstract. Flow-induced crystallization has been widely studied for a variety of polymers with the main focus on polyolefins. In this work, research has been conducted on the flow-induced ... flipping the scriptWebJan 1, 2024 · When polymer crystallization is induced by flow elongation, the semicrystalline morphology is affected by the orientation. The most obvious effects induced during flow are ascribed to kinetic and morphologic aspects, where in comparison with quiescent conditions the developed crystals trend to evolve from spherical to elongated … flipping the screen on a windows computerWebNov 22, 2013 · The so-called “short-term flow” protocol is widely applied in experimental flow-induced crystallization studies on polymers in order to separate the nucleation and subsequent growth processes [Liedauer et al. Int. Polym. Proc. 1993, 8, 236–244]. The basis of this protocol is the assumption that structure development during flow can be … greatest takeaway meaningWebFlow-Induced Crystallization of Poly(ether ether ketone): Universal Aspects of Specific Work Revealed by Corroborative Rheology and X-ray Scattering Studies. Macromolecules 2024 , 53 (22) , 10040-10050. flipping the script manipulationWebMar 30, 2024 · Understanding polymer crystallization with the presence of flow, or namely flow-induced crystallization (FIC), is crucial to optimize polymer processing parameters and to understand phase transition under far-from equilibrium conditions, as FIC is essentially a typical nonequilibrium process. Current review aims to summarizes recent ... flipping these birds song